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Sunitinib Malate
C22H27FN4O2·C4H6O5 532.57
Butanedioic acid, hydroxy-, (2S)-, compound with N-[2-(diethylamino)ethyl]-5-[(Z)-(5-fluoro-1,2-dihydro-2-oxo-3H-indol-3-ylidine)methyl]-2,4-dimethyl-1H-pyrrole-3-carboxamide (1:1);
N-[2-(Diethylamino)ethyl]-5-[(Z)-(5-fluoro-2-oxo-1,2-dihydro-3H-indol-3-ylidene)methyl]-2,4-dimethyl-1H-pyrrole-3-carboxamide hydrogen (2S)-2-hydroxybutanedioate [341031-54-7]

BRIEFING

Sunitinib Malate. Because there is no existing USP monograph for this drug substance, a new monograph based on validated methods of analysis is proposed. The proposal for this drug substance which appeared in PF 46(4) [Jul.– Aug. 2020] was canceled and is replaced with a new proposal.

  1. The liquid chromatographic procedure in the Assay is based on analyses performed with the XBridge Shield RP18 brand of column with L1 packing. The typical retention time for sunitinib is about 11 min.

  2. The liquid chromatographic procedure in the test for Organic Impurities is based on analyses performed with the XBridge Shield RP18 brand of column with L1 packing. The typical retention time for sunitinib is about 41 min.

Description and Solubility information: Yellow to orange powder. Soluble in dimethylsulfoxide; sparingly soluble in water at a pH of 1.2–6.8; practically insoluble in n-heptane.

 (SM3: S. Ramakrishna)

 Correspondence Number—C199050; C315839; C319588

USP REFERENCE STANDARDS FOR PURCHASE

USP Sunitinib Malate RS
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